MEV 018: Unit 12 – Environmental Monitoring of Toxicants
UNIT 12: ENVIRONMENTAL MONITORING OF TOXICANTS
12.0 Introduction
Toxicants—substances that cause adverse effects
on living organisms—can enter the environment through industrial, agricultural,
and urban activities. Environmental monitoring is a critical process used to
detect, quantify, and track these toxicants in various media such as air,
water, soil, and waste. It helps in risk assessment,
regulatory compliance, and environmental protection. This unit explores
different types of monitoring, sampling methods, and analytical techniques used
in environmental toxicant assessment.
12.1 Objectives
After studying this unit, learners will be able
to:
- Understand the purpose and importance of environmental monitoring.
- Describe the major types of environmental monitoring.
- Explain monitoring concepts, sampling methods, and analytical
techniques.
- Identify appropriate techniques for air, water, soil, and waste
analysis.
- Appreciate the role of monitoring in pollution control and public
health.
12.2 Types of Environmental
Monitoring
Environmental monitoring is classified based on
the environmental media and type of pollutant. The major categories include:
12.2.1 Air Quality Monitoring
- Purpose: To assess concentrations of air pollutants like SO₂, NOx, CO,
ozone, PM2.5, and volatile organic compounds (VOCs).
- Techniques:
- High Volume Samplers
- Gas analyzers (e.g., UV fluorescence for SO₂)
- Real-time monitoring stations
- Importance: Vital for tracking urban air pollution, occupational exposure,
and public health risks.
12.2.2 Water Quality
Monitoring
- Purpose: To detect pollutants such as heavy metals, pathogens, nitrates,
pesticides, and pH changes in surface water, groundwater, and wastewater.
- Parameters Monitored:
- Physical (temperature, turbidity)
- Chemical (pH, DO, BOD, COD, TDS, heavy
metals)
- Biological (coliform bacteria, algal blooms)
- Techniques:
- Spectrophotometry, Atomic Absorption
Spectroscopy (AAS), and microbial assays
12.2.3 Waste Monitoring
- Scope: Covers solid waste (municipal, industrial, biomedical) and liquid
effluents.
- Monitoring Aspects:
- Composition analysis
- Leachate quality in landfills
- Toxic content (e.g., dioxins, PCBs)
- Tools:
- TCLP (Toxicity Characteristic Leaching
Procedure)
- Gas chromatography for organic pollutants
12.2.4 Soil Monitoring
- Purpose: To detect contamination due to industrial discharge, pesticides,
fertilizers, and solid waste disposal.
- Analyzed for:
- Heavy metals (Pb, Cd, Hg)
- Hydrocarbons, pesticide residues
- Soil pH, cation exchange capacity (CEC),
nutrient status
- Techniques:
- Core sampling, X-ray fluorescence (XRF),
ICP-MS
12.3 Monitoring Concept and
Design
Environmental monitoring is guided by
scientifically sound designs and objectives. Key components include:
- Goal Definition: Regulatory compliance, pollution trend analysis, impact
assessment.
- Site Selection: Based on emission sources, population density, ecological
sensitivity.
- Temporal Design: Continuous, periodic, or event-based monitoring.
- Quality Assurance: Standard operating
procedures, calibration, control samples.
- Data Interpretation: Using baseline data,
comparison with permissible limits.
12.4 Environmental Sampling
Sampling is a crucial step to ensure accurate
results. It involves:
- Types of Sampling:
- Grab sampling (single time-point)
- Composite sampling (multiple time points or
locations)
- Sample Containers: Must be non-reactive,
sterile for biological samples, light-proof for light-sensitive
substances.
- Preservation and Transport: Use of cool boxes,
preservatives (e.g., nitric acid for metals), labeling, and
chain-of-custody documentation.
12.5 Techniques for Monitoring
The techniques used for monitoring depend on
the pollutant and environmental matrix. Common methods include:
- Spectrophotometry: For
analyzingcolor-forming reactions (e.g., nitrates, phosphates)
- Gas Chromatography (GC): For volatile organic
compounds (VOCs), pesticides
- High Performance Liquid Chromatography (HPLC): For
non-volatile organics
- Atomic Absorption Spectroscopy (AAS): For heavy metals like
lead, mercury
- Mass Spectrometry (MS): For high-precision
identification of complex molecules
- Biosensors: Detect specific toxicants using biological molecules (e.g.,
enzymes)
12.6 Environmental Analysis
Techniques
Post-sampling, analysis techniques aim to
quantify toxicants precisely:
- Gravimetric and Volumetric Methods: Basic estimation of
solids and ions
- Chromatographic Techniques: Separation and
identification of compounds (GC, HPLC)
- Electrochemical Methods: pH meters, conductivity
meters, ion-selective electrodes
- Biological Testing: Bioassays for toxicity
using algae, daphnia, or fish
Modern advancements also include:
- Remote Sensing: Satellite-based monitoring of air and water quality
- IoT-based Monitoring: Real-time sensor
networks for pollution hotspots
12.7 Let Us Sum Up
Environmental monitoring of toxicants is
essential for safeguarding ecosystems and human health. It includes a wide
range of activities such as air, water, soil, and waste quality assessments
using physical, chemical, and biological techniques. Accurate sampling,
rigorous analytical procedures, and data interpretation play a crucial role in
identifying pollution trends and guiding regulatory actions.
12.8 Key Words
- Toxicants: Harmful substances released into the environment.
- Environmental Monitoring: Systematic collection
of data to assess environmental quality.
- Air Quality Monitoring: Measuring air pollutant
concentrations.
- Water Quality Parameters: Indicators of chemical
and biological water health.
- Chromatography: Technique to separate and analyze mixtures.
- Biosensors: Analytical devices using biological components to detect
pollutants.
- Remote Sensing: Monitoring using satellite imagery or aerial technology.
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